FAJRIN, ARFYANTI (2016) SINTESIS UiO-66 PADA PENDUKUNG SILIKA MESOPORI. Undergraduate thesis, Institut Teknologi Sepuluh Nopember.
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Abstract
Zirkonium-benzendikarboksilat (Zr-BDC) atau UiO-66,
telah disintesis dengan metode solvotermal menggunakan reaktan
ZrCl4 dan asam 1,4-benzendikarboksilat dengan pelarut DMF pada
suhu 120 ̊ C selama 24 jam. Selain itu UiO-66 juga disintesis dengan
pendukung silika mesopori (UiO-66/MCM-41) menggunakan
metode yang sama dengan variasi massa silika mesopori 50, 100, dan
200 mg. Padatan yang diperoleh dikarakterisasi dengan XRD, FTIR,
SEM-EDX, TGA, dan adsorpsi-desorpsi nitrogen. Semua material
yang telah disintesis memiliki puncak difraktogram pada sudut 2θ =
7,4o dan 8,5o dengan intensitas dan pelebaran yang berbeda
denganintensitas UiO-66. Material UiO-66 dan UiO-66/MCM-41
memiliki morfologi yang hampir sama, yaitu bulatan kecil-kecil yang
bergerombol. Semua material menunjukkan kestabilan termal antara
455-513 ̊ C dengan luas permukaan spesifik UiO-66 (497 m2/g) lebih
rendah dibanding UiO-66/MCM-41(50) (614 m2/g) dan UiO-
66/MCM-41(200) 548 m2/g.
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Zirconium-benzenedicarboxylate or UiO-66, has been
synthesized by the method solvothermal using ZrCl 4 reactant
and the acid 1,4-benzendikarboksilat with the solvent DMF at
120 ̊ C for 24 hours. In addition UiO-66 is also synthesized by
supporters of mesoporous silica (UiO-66/MCM-41) using the
same method with mesoporous silica mass variation of 50, 100,
and 200 mg. The solids obtained were characterized by XRD,
FTIR, SEM-EDX, TGA, and nitrogen adsorption-desorption.
All the materials have been synthesized have diffractogram
peaks at angles 2θ = 7,4 ̊ and 8,5 ̊with different intensity and
widening the intensity UiO-66. Material UiO-66 and UiO-
66/MCM-41 has a similar morphology , namely small dots are
clustered. All the material shows thermal stability between
455-513 ̊ C with a specific surface area UiO-66 (497 m2/g)
lower than UiO-66/MCM-41(50) (614 m2/g) and UiO-
66/MCM- 41(200) 548 m2/g.
| Item Type: | Thesis (Undergraduate) |
|---|---|
| Additional Information: | RSKi 541.345 13 Faj s |
| Uncontrolled Keywords: | Silika mesopori, Zr-BDC, UiO-66/MCM-41, Solvotermal, Kloroform, DMF |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | Faculty of Mathematics and Science > Chemistry > 47201-(S1) Undergraduate Thesis |
| Depositing User: | Mr. Tondo Indra Nyata |
| Date Deposited: | 16 Jan 2017 04:18 |
| Last Modified: | 26 Dec 2018 07:33 |
| URI: | http://repository.its.ac.id/id/eprint/1604 |
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