A non-catalytic in situ process to produce biodiesel from a rice milling by-product using a subcritical water-methanol mixture

Zullaikah, Siti and Rahkadima, Yulia T. and Ju, Yi-Hsu (2017) A non-catalytic in situ process to produce biodiesel from a rice milling by-product using a subcritical water-methanol mixture. A non-catalytic in situ process to produce biodiesel from a rice milling by-product using a subcritical water-methanol mixture, 111 (1). pp. 764-770. ISSN 0960-1481

[img]
Preview
Text
A non catalytic in situ process to produce biodiesel from a rice milling by product using a subcritical water methanol mixture.pdf - Published Version

Download (1MB) | Preview
Official URL: http://www.sciencedirect.com/science/article/pii/S...

Abstract

A non-catalytic method to produce biodiesel in situ from a rice milling by-product, i.e. rice bran, using subcritical water-methanol mixture has been investigated. The method was found to be unaffected by initial moisture and free fatty acids (FFA) contents in rice bran so that no pretreatment was required. The yield and purity of biodiesel were higher under CO2 atmosphere than those under N atmosphere due the ability of the gas to acidify water-methanol mixture. Oil extraction from the bran was identified as the limiting step and complete oil extraction could be achieved in 3 h at 200oC, 4 MPa (under CO2 atmosphere) and 43.8 wt% methanol concentration. Consequently, the highest biodiesel yield was also achieved at those operating conditions. The experimental data suggested that hydrolysis of rice bran oil into FFA followed by methyl-esterification of FFA into biodiesel could be the preferred reaction path to direct transesterification of oil. Subcritical water-methanol mixture was also able to break down complex carbohydrates in rice bran into simple sugars soluble in aqueous phase so that it could be separated easily from biodiesel.

Item Type: Article
Additional Information: 621.43 Zul a
Uncontrolled Keywords: Biodiesel Rice bran Subcritical water-methanol In situ process Non-catalytic process
Subjects: T Technology > TP Chemical technology > TP156 Crystallization. Extraction (Chemistry). Fermentation. Distillation. Emulsions.
Divisions: Faculty of Industrial Technology > Chemical Engineering
Depositing User: Siti Zullaikah
Date Deposited: 13 Dec 2017 02:37
Last Modified: 13 Dec 2017 02:37
URI: http://repository.its.ac.id/id/eprint/43926

Actions (login required)

View Item View Item