Sintesis Komposit Fe2O3/HKUST-1 Serta Aplikasinya Sebagai Adsorben Metilen Biru Dalam Air

Ria, Furi Dina (2021) Sintesis Komposit Fe2O3/HKUST-1 Serta Aplikasinya Sebagai Adsorben Metilen Biru Dalam Air. Undergraduate thesis, Institut Teknologi Sepuluh Nopember.

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Abstract

Sintesis HKUST-1 dan komposit Fe2O3/HKUST-1 telah berhasil dilakukan dengan metode solvotermal pada suhu 100 °C selama 10 jam dalam pelarut DMF:Etanol:AquaDM dengan perbandingan volume (1:1:1). Penambahan Fe2O3 dilakukan dengan variasi massa sebesar 5, 10, dan 20% terhadap massa HKUST-1. Material yang dihasilkan dinotasikan sebagai Fe(5)/HKUST-1, Fe(10)/HKUST-1 dan Fe(20)/HKUST-1, kemudian dikarakterisasi menggunakan XRD, FTIR, dan SEM-EDX. Difraktogram XRD semua material hasil sintesis menunjukkan puncak karakteristik yang sama dengan HKUST-1 standar. Spektra FTIR material hasil sintesis menunjukkan pita serapan pada bilangan gelombang yang sama dengan HKUST-1 dan Fe2O3 yang telah dilaporkan. Morfologi Fe2O3/HKUST-1 berupa kristal oktahedral yang hampir sama dengan morfologi HKUST-1 standar. Hasil uji adsorpsi metilen biru (MB) menunjukkan bahwa Fe(20)/HKUST-1 memiliki kapasitas adsorpsi tertinggi sebesar 222,222 mg/g serta mengikuti model kinetika adsorpsi orde dua semu dan isotermal adsorpsi Langmuir.
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Synthesis of HKUST-1 and Fe2O3/HKUST-1 composites have been succesfully carried out with solvothermal method at 100 °C for 10 hours in DMF:Etanol:AquaDM solvents with volume ratio 1:1:1. The Fe2O3 was added to the reaction mixture with mass variations of Fe2O3, i.e. 5, 10, and 20% toward the mass of HKUST-1. The obtained materials were denoted as Fe(5)/HKUST-1, Fe(10)/HKUST-1, and Fe(20)/HKUST-1, then characterized by XRD, FTIR, and SEM-EDX. The diffractogram patterns of the synthesized materials showed similarity to that of HKUST-1 standard. FTIR spectra of the synthesized materials showed absorption bands at the same wavenumbers as reported for HKUST-1 and Fe2O3. The morphology of Fe2O3/HKUST-1 had the same shape as the HKUST-1. The results of the adsorption methylene blue (MB) showed that Fe(20)/HKUST-1 had the highest adsorption capacity of 222,222 mg/g, and followed the pseudo second order adsorption kinetics and Langmuir isothermal adsorption.

Item Type:	Thesis (Undergraduate)
Uncontrolled Keywords:	HKUST-1, Fe2O3, Fe2O3/HKUST-1 Composite, Adsorption, Methylene blue, HKUST-1, Fe2O3, Komposit Fe2O3/HKUST-1, Adsorpsi, Metilen biru
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Natural Science > Chemistry > 47201-(S1) Undergraduate Thesis
Depositing User:	Furi Dina Ria
Date Deposited:	23 Aug 2021 01:23
Last Modified:	23 Aug 2021 01:23
URI:	http://repository.its.ac.id/id/eprint/88522

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