Nafi’, Moch Ahdian Wildan (2022) Pengaruh Lingkungan Sulfat Terhadap Beton Geopolimer Berbahan Dasar Fly Ash Tipe C. Diploma thesis, Institut Teknologi Sepuluh Nopember.
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Abstract
Lingkungan laut agresif terhadap beton, karena mengandung senyawa klorida dan sulfat. Kehadiran sulfat mengarah pada pembentukan thaumasite, ettringite dan gipsum yang berkontribusi terhadap keretakan, kehilangan kekuatan dan pengelupasan beton. Oleh karena itu dibutuhkan inovasi semen yang dapat menahan serangan sulfat. Beton geopolimer merupakan beton yang dibuat tanpa campuran semen Portland , bahan dasar beton geopolimer berasal dari campuran fly ash dan alkali aktivator. Umumnya fly ash yang digunakan pada penelitian sebelumnya adalah low calcium namun di Indonesia fly ash yang sering dijumpai adalah high calcium. Dari hasil penelitian sebelumnya high calcium memiliki kelemahan pada setting time yang lebih cepat dibandingkan low calcium sehingga diperlukan superplatisizer berupa sukorsa untuk mengurangi waktu ikat beton geopolimer. Penelitian ini dilakukan untuk mengetahui pengaruh sulfat terhadap beton geopolimer berbahan dasar fly ash tipe C dengan Natrium Hidroksida dan Natrium silikat sebagai alkali aktivator. Selain itu, Penelitian ini juga menggunakan superplastisizer berupa sukrosa. Kuat tekan beton dan massa beton yang direndam pada magnesium sulfat akan ditinjau pada penelitian ini. Sebelum dilakukan perendaman pada magnesium sulfat, beton akan dilakukan perawatan ambient terlebih dahulu selama 28 hari. Selain itu pH larutan magnesium sulfat juga akan diuji untuk mengetahui perubahan nilai keasaman dari larutan. Penelitian ini menggunakan benda uji silinder ukuran 10 cm x 20 cm dengan metode pencampuran kering dan target kuat tekan sebesar 28 MPa sesuai SNI 2847 – 2019. Hasil penelitian menunjukkan bahwa kuat tekan beton telah memenuhi standar SNI 2847-2019 untuk implementasi di lingkungan sulfat dengan klasifikasi S1, yaitu lebih dari 28 MPa dan nilai slump berada pada rentang 150-230 mm sesuai syarat SNI 1972-2008. Nilai FAS beton geopolimer sebesar 0,235 < 0,5 sehingga telah memenuhi SNI 2847-2019. Hasil uji kuat tekan pada beton geopolimer setelah 28 hari direndam dengan larutan magnesium sulfat, kuat tekan beton geopolimer mengalami peningkatan terlebih dahulu yaitu menjadi 50,89 Mpa. Kemudian kuat tekan menjadi 48,04 Mpa pada saat beton terendam selama 56 hari. Setelah itu, kuat tekan mengalami penurunan lagi hingga mencapai 39,98 Mpa setelah terendam magnesium sulfat selama 84 hari. Sedangkan hasil uji kuat tekan dengan Ambient Curing cenderung stabil yaitu di kisaran antara 42 – 43 Mpa. Untuk perubahan massa beton geopolimer yang direndam oleh magnesium sulfat selama 84 hari mengalami penurunan sebesar 0,02% dari kondisi semula. Sedangkan massa beton geopolimer yang dilakukan perawatan Ambient mengalami penurunan sebesar 0,22% dari kondisi semula.
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The marine environment is aggressive to concrete, as it contains chloride and sulfate compounds. The presence of sulfates will form thaumasite, ettringite and gypsum which contribute to cracking, loss of strength and peeling of the concrete. Therefore, it is necessary to innovate cement that can withstand sulfate attack. Geopolymer concrete is a concrete made without a mixture of Portland cement, the base material for geopolymer concrete comes from a mixture of fly ash and alkali activator. Generally, the fly ash used in previous studies is low calcium, but in Indonesia the fly ash that is often found is high calcium. From the results of previous studies, high calcium has a weakness in setting time which is faster than low calcium, so a superplatisizer in the form of sucrose is needed to reduce the bonding time of geopolymer concrete. This research was conducted to determine the effect of sulfate on geopolymer concrete made from fly ash type C with sodium hydroxide and sodium silicate as alkali activator. Furthermore, this study also used a superplasticizer in the form of sucrose. The compressive strength of concrete and the mass of concrete immersed in magnesium sulfate will be reviewed in this study. Before immersion in magnesium sulfate, the concrete will be subjected to ambient treatment for 28 days. In addition, the pH of the magnesium sulfate solution will also be tested to determine changes in the value of the solution. This study uses a cylindrical specimen measuring 10 cm x 20 cm with a dry mixing method and a target compressive strength of 28 MPa according to SNI 2847 – 2019. The results showed that the compressive strength of the concrete had fulfilled the SNI 2847-2019 standard for implementation in the sulfate environment with the S1 classification, which was more than 28 MPa and the slump value was in the range of 150-230 mm according to the requirements of SNI 1972-2008. The FAS value is 0,235 < 0,5 so that it fulfill SNI 2847- 2019. The results of the compressive strength test on geopolymer concrete after 28 days of immersion in magnesium sulfate solution, the compressive strength of geopolymer concrete increased to 50,89 Mpa. Then the compressive strength becomes 40,4 MPa when the concrete is immersion for 56 days. After that, the compressive strength decreased again to 39,98 MPa after immersion in magnesium sulfate for 84 days. As a comparison, the results of the compressive strength test with Ambient Curing tend to be stable in the range between 42 - 43 MPa. For changes in the mass of geopolymer concrete immersion in magnesium sulfate for 84 days, it decreased by 0,02% from its original condition. Meanwhile, the mass of geopolymer concrete that was treated with ambient decreased by 0,22% from its original condition.
| Item Type: | Thesis (Diploma) |
|---|---|
| Additional Information: | RSIS 620.136 Naf p-1 2022 |
| Uncontrolled Keywords: | Beton Geopolimer, Fly Ash Tipe C, Magnesium Sulfat, Perubahan Masaa, Kuat Tekan. Geopolymer Concrete, High Calcium Fly Ash, Magnesium Sulfate, Mass Change, Compressive Strength. |
| Subjects: | T Technology > TA Engineering (General). Civil engineering (General) |
| Divisions: | Faculty of Vocational > 22301-Civil Infrastructure Engineering (D4) |
| Depositing User: | Mr. Marsudiyana - |
| Date Deposited: | 10 Jul 2026 06:54 |
| Last Modified: | 13 Jul 2026 01:12 |
| URI: | http://repository.its.ac.id/id/eprint/134643 |
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