Suci, Farradina Choria (2015) Adsorpsi Hidrogen pada Material Karbon Tertemplat Zeolit-Y dengan Aktivasi K2CO3. Masters thesis, Institut Teknologi Sepuluh Nopember.
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Abstract
Penggunaan teknologi hidrogen sebagai sumber energi pada sel bahan bakar kendaraan bermotor masih memiliki kendala terutama dalam penyimpanan hidrogen. Zeolit templat karbon yang diaktivasi dengan K2CO3 merupakan material dengan porositas tinggi dan luas permukaan yang besar. Hasil kapasitas adsorpsi hidrogen pada 30°C, 40°C dan 50°C adalah 3,206; 2,885 dan 2,458% berat, berturut-turut. Peningkatan kapasitas adsorpsi hidrogen dipengaruhi oleh suhu adsorpsi. Peningkatan suhu adsorpsi, menurunkan kapasitas adsorpsi hidrogen. Kapasitas adsorpsi hidrogen tertinggi diperoleh 3,821% berat pada suhu 30°C dan tekanan 3 bar. Model isoterm adsorpsi mengikuti model Langmuir yang didasarkan pada nilai koefisien korelasi regresi. Disisi lain, berdasarkan hasil karakterisasi XRD, SEM dan N2 adsorpsi-desorpsi mengindikasikan permukaan adsorbat yang heterogen sesuai model Freundlich. Parameter termodinamik menunjukkan bahwa adsorpsi berlangsung secara eksotermis dengan nilai ΔH°
-18,610 kJ/mol. Proses adsorpsi mengikuti prinsip fisisorpsi karena nilai ΔH° kurang dari 80 kJ/mol. Adsorpsi berlangsung spontan yang dikonfirmasi melalui ΔG° yang bernilai negatif (-2,054; -1,058 dan -0,961 kJ/mol). Nilai perubahan entropi (ΔS°) yang bernilai negatif menunjukkan penurunan ketidakaturan antara permukaan gas-solid saat proses adsorpsi.
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The utilization of hydrogen as a source of energy technologies in vehicle fuel cells still have a problem especially in the storage of hydrogen. Zeolite Templated Carbon (ZTC) activated K2CO3 is a material with high porosity and large surface area. Results of hydrogen adsoption capacity at 30 °C, 40 °C, and
50 °C were 3.206, 2.885, and 2.458 %w, respectively. The amount of hydrogen adsorption capacity was affected by adsorption temperature. The increase of adsoption temperature, the decrease hydrogen adsorption. The highest hydrogen adsorption capacity was obtained 3.821%w at 30°C and pressure of 3 bar. Model isotherm adsorption results indicated that Langmuir model provided the best fit for the equilibrium data. In the other hand, based on the characterization results of XRD, SEM and N2 adsorption-desorption indicated a heterogeneous surface adsorbate corresponding Freundlich models. Thermodynamics parameters showed that adsorption process was exothermic as confirmed by the enthalpy (ΔH°) of -18.610 kJ/mol. Adsorption process followed the principles of physisorption because ΔH° values less than 80 kJ/mol. Adsorption through spontaneously confirmed by free energy change (ΔG°) of (-2.054, -1.058 dan -0.961 kJ/mol). The entropy change (ΔS°) was positive that indicated weak of enthropy gas-solid surface during adsoprtion process.
| Item Type: | Thesis (Masters) |
|---|---|
| Additional Information: | RTKi 549.68 Suc a |
| Uncontrolled Keywords: | karbon tertemplat zeolit-Y, material penyimpan hidrogen, adsorpsi hidrogen, zeolite-Y templated carbon, hydrogen storage material, hydrogen adsorption |
| Subjects: | Q Science > QD Chemistry Q Science > QD Chemistry > QD547 Flocculation, precipitation, adsorption, etc. |
| Divisions: | Faculty of Mathematics and Science > Chemistry > 47101-(S2) Master Thesis |
| Depositing User: | Eny Widiastuti - |
| Date Deposited: | 24 May 2018 02:46 |
| Last Modified: | 24 Aug 2018 06:55 |
| URI: | http://repository.its.ac.id/id/eprint/51940 |
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